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NC Department of Health and Human Services
Hazardous Substances Emergency Events Surveillance Program
Mercury Facts
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Table of Contents
Significance of Mercury (Hg) in the United
States
CAS # 7439-97-6
Mercury is a naturally occurring metal which has several forms. At room
temperature, metallic mercury is a heavy, shiny, silver, odorless liquid. When
heated, mercury becomes a colorless, odorless gas. Metallic mercury is used to
produce chlorine gas and caustic soda. Mercury is also used in
thermometers, dental fillings, batteries and switches.
Mercury Releases in North Carolina
The information in this report was collected by staff in the North Carolina
Hazardous Substances Emergency Events Surveillance (HSEES) Program. Mercury
releases in North Carolina have resulted in injuries and hospitalizations
(Table 1). Some examples of Mercury releases in NC
include:
- A group of children found a small baby food jar of mercury. They
spilled the contents, causing several children and adults to be contaminated
with mercury. All were transferred to a local medical facility for
evaluation.
- A nurse was decontaminated after a wall-mounted blood pressure unit was
broken and mercury was released onto her hands. She was not injured, but the
mercury destroyed her wedding ring.
- Old mercury-containing switches at a water treatment plant leaked. No
one was injured or required decontamination, but contaminated soil was removed
and disposed of properly.
- An airline passenger had one pound of mercury packed in his luggage.
During baggage handling, the luggage was dropped and the container of mercury
was broken. Fifteen employees had to be decontaminated, and five were taken to
the hospital and treated for skin irritation.
Of the 21 mercury releases that occurred between 1993 and 2001 in North
Carolina, 20 (95%) occurred in fixed facilities and one (5%) took place in
transit. Most of the fixed-facility events resulted from unintended releases
involving either material handling or above-ground storage vessels.
Efforts to identify the factors contributing to chemical releases were
initiated in mid-1995. Since then, human error (N=8, 42%) and equipment
failure (N=4, 21%) have been cited as the major contributing factors,
responsible for 63% (12) of the 19 mercury events for which this information is
available. The 21 events occurring between 1993 and 2001 are summarized in
Table 1. Table 2
lists the types of industries involved in Mercury releases. Locations of
Mercury releases are shown in Map 1.
Table 1: Summary of HSEES Data on Mercury Releases in North Carolina, 1993-2001
| Data |
Number |
|
| Number of mercury release spills | 21 |
| Number of events involving victims | 1 |
| Number of victims | 5 |
|
| Types of injuries |
| Skin irritation |
5 |
|
| Range of amounts released (pounds) |
>1 to 5 |
|
| Events with decontamination |
| No. of events with general public decontaminated |
5 |
| No. of events with employees decontaminated |
20 |
|
| Number of events following a contingency/preparedness plan |
21 |
|
| Type of response |
| HAZMAT/response team's
standard operating procedure | 11 |
| Company's operating procedures | 4 |
| Incident-specific |
4 |
| Other |
1 |
| Unknown |
1 |
|
| Total |
21 |
|
Table 2: Industries Involved in Mercury Releases in North Carolina,
1993-2001
| Type of NC Industry Releasing Mercury |
No. of Events |
Percentages |
| Air transportation | 2 | 9.5 |
| Schools - Elementary, secondary, colleges and universities | 3 | 14.3 |
| Hospitals | 5 | 23.8 |
| Industrial and miscellaneous chemicals | 2 | 9.5 |
| Nursing and personal care facilities | 3 | 14.3 |
| Other | 6 | 28.6 |
| Total | 21 | 100 |
Common Routes of Mercury Exposure
- Inhalation. Mercury may enter the body through the respiratory
system. Serious respiratory disturbances result from inhalation exposure to
mercury.
- Contact with the Skin. Mercury can irritate the skin. Mercury may
also be absorbed through the skin.
- Contact with the Eyes. Mercury or mercury vapor can be absorbed into
the body through the eyes. Mercury may irritate the eyes.
Acute Health Effects of Mercury Exposure
Acute exposures to high levels of mercury can cause headaches, nausea,
diarrhea, cough, chest pains, chest tightness, and difficulty breathing
depending on the route of exposure. Exposure to high levels of
mercury damages the brain, kidneys and developing fetus. Liquid mercury may
irritate the skin.
Chronic Health Effects of Repeated Exposure to Mercury
Effects develop gradually with chronic low-level exposure. Fine tremors of
the hands, eyelids, lips and tongue are often signs of chronic mercury liquid
or vapor exposure. Psychic disturbances such as insomnia, irritability and
indecision may occur. Headache, excessive fatigue, anorexia, digestive
disturbances, and weight loss are common. Skin rashes, sores in the mouth,
sore and swollen gums, loose teeth, and excess salivation may also occur with
repeated exposures to mercury liquid or vapor.
Proper Handling and Storage Procedures for Mercury
Before working with mercury, individuals should be trained in its proper
handling and storage and know how to use proper personal protective
equipment.
Mercury should be stored in a cool, dry, well-ventilated area in tightly
sealed containers protected from exposure to weather and physical damage.
Mercury is incompatible with acetylenes, ammonia, ethylene oxide, chlorine
dioxide, azides, metal oxides, methyl silane, lithium, rubidium, oxygen, strong
oxidants, and metal carbonyls. Contact with these substances may produce
hazardous vapors or form solid products that are sensitive to shock, which can
initiate fires of combustible materials. Mercury may also attack copper and
copper alloy materials.
Personal Protective Equipment
- Clothing
Avoid skin contact with mercury. Wear impervious clothing, boots, and
protective gloves.
- Eye Protection
Employees should use a minimum eight-inch face shield or chemical safety
goggles when there is any possibility of mercury exposure.
- Respiratory Protection (respirators)
Engineering controls should be implemented to reduce environmental
concentrations to the OSHA permissible exposure level (0.1 mg/m 3 ).
Respirators with a mercury vapor or chlorine gas cartridge should be used when
engineering and work practice controls are not feasible or are being installed.
Respiratory protection should be approved by NIOSH or the Mine Safety and Health
Administration and used in accordance with the OSHA Respiratory Protection
Standard, 29 CFR (Code of Federal Regulations) 1910.134. Respirator use must be
limited to individuals who have been medically cleared, adequately trained, and
fitted for the respirator face-piece.
First Aid Management
Prompt action is essential if there is a mercury spill. If a mercury leak
occurs, take the following actions:
- Breathing
If mercury is inhaled, move the person to fresh air at once. If breathing stops,
perform artificial respiration. Keep the affected person warm and resting.
Seek medical attention immediately.
- Eye Exposure
Wash eyes immediately with large amounts of water for at least 15 minutes,
lifting the upper and lower lids. Seek medical attention immediately. Contact
lenses should not be worn when working with mercury.
- Skin Exposure
Skin contaminated with mercury should be flushed with soap and water for at
least 15 minutes. If irritation persists after washing, seek medical
attention.
- Swallowing
If a person has swallowed mercury, do not induce vomiting. Rinse out the mouth with water and seek medical attention by contacting a physician or calling the poison control center (1-800-222-1222).
Spill Management
Small Spills (Less than 10 grams [a pool about the size of a quarter])
- Prevent the mercury from spreading with towels or tissues.
- Remove contaminated clothing or shoes and place in a trash bag.
- Evacuate and restrict people from the area of the mercury release.
- Do NOT use household vacuum cleaners for cleanup.
- Do NOT use a broom or paint brush for cleanup as this will
break the mercury beads and cause them to spread.
- Do NOT use household cleaning products to clean the spill.
Many products contain chemicals that react with mercury and cause a toxic gas to form.
- Collect the spilled material for reclamation using commercially available
mercury vapor depressants, sulfur compounds to coat and make an amalgam of the
spilled mercury, or specialized vacuum cleaners.
| Useful Items for Small Spill Cleanup |
- Commercially available “Mercury Spill Kit” or
- Rubber squeegee
- Plastic dust pan
- Plastic trash bags
- Zipper-shut plastic bags
- Wide-mouth plastic container with tight lid
- Large tray or box
- Facial tissues, toilet paper, or paper towels
- Eye dropper
- Index cards, playing cards, or other disposable heave paper
- Plastic wrap
- Sulfur powder
- Zinc or copper flakes
- Tape (for picking up very small particles)
|
Large Spills (More than one pound or two tablespoons)
- Untrained persons or those without proper personal protective equipment
and clothing must not enter areas until the mercury spill has been cleaned up.
- For large spills of more than one pound (two tablespoons), notify the
National Response Center at 1-800-424-8802 and your local
emergency planning committee (LEPC) of the spill.
- A professional should handle the clean-up procedure for large mercury spills.
- Evacuate and restrict people from the hazardous area of a mercury release.
- Ventilate contaminated area to the outdoors.
- To prevent evaporation of the mercury, lower the room temperature.
North Carolina HSEES Program
The North Carolina Department of Health and Human Services - Division of
Public Health studies and describes the public health effects associated with
releases of hazardous substances such as mercury, as part of the Agency for
Toxic Substances and Disease Registry’s (ATSDR) Hazardous Substances
Emergency Events Surveillance (HSEES) system. North Carolina is one of 16
participating states. Data are analyzed to determine trends and areas for
prevention. The information is then used to develop ways to protect health and
prevent or minimize hazardous substance releases.
The HSEES staff is notified about spills by several sources. The primary
sources of information are the N.C. Division of Emergency Management, the U.S.
Coast Guard’s National Response Center, and the U.S. Department of
Transportation’s Hazardous Materials Information System (HMIS). To gather
specific information about each spill, staff contact local emergency management
personnel, fire department personnel, emergency medical personnel, and/or
industry representatives.
To plan appropriate prevention strategies, we rely on accurate and timely
reporting. If you are contacted about a hazardous chemical spill, please
answer the questions as precisely and accurately as possible. The information
you provide is critical to preventing future spills and reducing the risk of
injury to employees, responders and the public. Contact the N.C. HSEES Program
at 919-733-1145 or visit our web site.
Resources and Information
Occupational Safety and Health Administration (OSHA)
OSHA provides specific information about proper handling, storage, and
safety and health management of mercury. Publications can be obtained by
written request or through the OSHA web page.
-
OSHA Publications Office,
200 Constitution Avenue NW
Room N3101
Washington, DC 20210
(202) 219-8151
www.osha.gov
-
North Carolina OSHA
4 West Edenton St
Raleigh, NC 27601-1092
(919) 807-2860
www.dol.state.nc.us/osha/osh.htm
- National Institute of Occupational Safety and Health (NIOSH)
NIOSH Publications
4676 Columbia Parkway, Mail Stop C-13
Cincinnati, OH 45226-1998
1-800-35-NIOSH (1-800-356-4674)
http://www.cdc.gov/niosh/homepage.html
- Environmental Protection Agency (EPA)
Ariel Rios Building
1200 Pennsylvania Avenue, NW
Washington, DC 20460
202-260-2090
www.epa.gov
- Region IV EPA (includes North Carolina)
Atlanta Federal Building
61 Forsyth Street, SW
Atlanta, GA 30303-3104
404-562-9900
1-800-241-1754
- North Carolina Department of Health and Human Services
Occupational and Environmental Epidemiology Branch
HSEES Program
1912 Mail Service Center
Raleigh, NC 27699-1912
(919) 733-3410
www.schs.state.nc.us/epi/oii/hsees.html
References
U.S. Department of Health, Education, and Welfare. Public Health Service,
Centers for Disease Control, National Institute for Occupational Safety and
Health. Occupational Diseases - A Guide to Their Recognition.
Ed. Marcus M. Key, M.D., et al. Washington, D.C.: DHEW (NIOSH), 1978.
NC Department of Health and Human Services
Division of Public Health
Occupational & Environmental Epidemiology Branch
Hazardous Substances Emergency Events Surveillance
1912 Mail Service Center
Raleigh, NC 27699-1912
State of North Carolina
Beverly Eaves Perdue, Governor
Department of Health and Human Services
Division of Public Health
http://www.ncpublichealth.com
The NC Department of Health and Human Services does not discriminate on
the basis of race, color, national origin, sex, religion, age or disability
in employment or the provision of services.
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